Line Intensity and Position Measurements and Derived Band Parameters of the 31103-00001 C-12 O-16(2) Band and its Two Nearby Hot Bands

A set of CO2 spectra from 4500 to 4780/cm has been obtained an Ames with 1500 m path length using a Bomem DA8 FTS. This spectral region contains a number of weak bands and minor isotopic bands that have been studied at high resolution in the reflection spectrum of Venus by Mandin. Improved laboratory intensity and position measurements should assist modeling the Venus reflection spectra and improve understanding of Venus' upper atmosphere. Also, the laboratory measurements will assist DND intensity computations of weaker bands that cannot be measured, but which are nevertheless significant absorbers in Venus' hot, deep CO2, atmosphere. For example, some of the weaker bands that are members of the same polyads as the bands in this presentation lie in the nearby 2.3 microns emission window in Venus' night-side spectrum.