High Temperature mechanically pumped fluid loop for space applications - working fluid selection

Mechanically pumped single-phase fluid loops are increasingly being used for heat rejection purposes in space applications. Examples of Earth orbiting missions using this technology include NSTS Shuttles (water and Freon-based loops) and the International Space Station (water and ammonia-based loops). For deep space missions, both the Mars Pathfinder (1996) and Mars Exploration Rover (2003) missions used mechanically pumped Freon-I 1 loops for their primary Heat Rejection Systems (HRS.) Mechanically pumped loops are particularly well suited for rejecting large amounts of waste heat from spacecraft and future missions incorporating components with extremely high thermal energy dissipation (e.g. radar instruments, Radioisotope-based power sources) are ideal candidates for their use. However, previous implementations of mechanically pumped loops were designed for moderate temperatures (below 6OOC) and, thus, would require relatively large radiators to reject high heat loads to space. Loops designed for a higher operating temperature would allow large amounts of heat to be rejected within the constraints of a mass efficient thermal control system.