Slip-boundary equations for multicomponent nonequilibrium airflow

Equations are presented for the surface-slip (or jump) values of species concentration, pressure, velocity, and temperature in the low Reynolds number, high-altitude flight regime of a space vehicle. These are obtained from closed-form solutions of the mass, momentum, and energy flux equations by using the Chapman-Enskog velocity distribution function. This function represents a solution of the Boltzmann equation in the Navier-Stokes approximation. The analysis, obtained for nonequilibrium multicomponent airflow, includes the finite-rare surface catalytic recombination and changes in the internal energy during reflection from the surface. Expressions for the various slip quantities have been obtained in a form which can readily be employed in flow-field computations. A consistent set of equations is provided for multicomponent and binary mixtures and single-species gas. An expression is also provided for the finite-rate species-concentration boundary condition for a multicomponent mixture in the absence of slip.