Corrosion Resistance of Materials in the Mars Environment

This paper presents the results of a literature search of available data relevant to corrosion resistance of materials in the Mars environment, as a background for future experimental work. Corrosion resistance is one of the most important properties in selecting materials for landed spacecraft and structures that will support surface operations for the human exploration of Mars. Currently, the selection of materials is done by assuming that the corrosion behavior of a material on Mars will be the same as that on Earth. This is understandable since there is no data available on the corrosion resistance of materials in the Mars environment. However, given that corrosion is defined as the degradation of a metal that results from its chemical interaction with the environment, it cannot be assumed that corrosion is going to be the same in both environments, since they are significantly different. This theoretical study was motivated by the suggestion, by a team of researchers, that some of the structural degradation observed on Curiosity's wheels may have been caused by corrosive interactions with the transient liquid brines, reported to be present on Mars, while the most significant damage was attributed to mechanical damage. An extensive literature search, on data relevant to corrosion on Mars, confirmed the need to investigate the interaction between materials, used for spacecraft and structures designed to support long-term surface operations on Mars, and the Mars environment. Experimental studies are needed to investigate the corrosion behavior of materials in relevant components of the Mars environment such as: the Mars atmosphere, the presence of brines, the interaction between these brines and materials, the effect of radiation on these interactions, and the possible catalytic effects of the clays present in the Martian regolith. The findings from this theoretical study provide strong justification to conduct experimental work to investigate the interaction between spacecraft materials with simulated Martian environments to reduce Mars exploration costs.