A mathematical model for jet engine combustor pollutant emissions

Mathematical modeling for the description of the origin and disposition of combustion-generated pollutants in gas turbines is presented. A unified model in modular form is proposed which includes kinetics, recirculation, turbulent mixing, multiphase flow effects, swirl and secondary air injection. Subelements of the overall model were applied to data relevant to laboratory reactors and practical combustor configurations. Comparisons between the theory and available data show excellent agreement for basic CO/H2/Air chemical systems. For hydrocarbons the trends are predicted well including higher-than-equilibrium NO levels within the fuel rich regime. Although the need for improved accuracy in fuel rich combustion is indicated, comparisons with actual jet engine data in terms of the effect of combustor-inlet temperature is excellent. In addition, excellent agreement with data is obtained regarding reduced NO emissions with water droplet and steam injection.