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Gauge invariance, current conservation, and GIAO's.The well-known relationship between gauge invariance and current conservation is exhibited within the usual quantum mechanical formalism. It is then shown that the use of Gauge Invariant Atomic Orbitals does not necessarily lead to the expected current conservation. The reason is found to lie in the constrained nature of the gauge invariance which is provided by the use of GIAO's. It is concluded that this invariance is, of itself, no argument in favor of their use.
Document ID
19730039443
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Epstein, S. T.
(Wisconsin, University Madison, Wis., United States)
Date Acquired
August 7, 2013
Publication Date
February 15, 1973
Publication Information
Publication: Journal of Chemical Physics
Volume: 58
Subject Category
Physics, Atomic, Molecular, And Nuclear
Accession Number
73A24245
Funding Number(s)
CONTRACT_GRANT: NGL-50-002-001
Distribution Limits
Public
Copyright
Other

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