Atomic nitrogen densities in the thermosphere

Recently atomic nitrogen densities of about one million per cu cm were measured at 400 km by the open source mass spectrometer on the Atmosphere Explorer-C satellite (AE-C). Daytime N densities about 50 million per cu cm at 160 km have also been inferred from airglow and other measurements on AE-C. It is shown that atomic nitrogen densities of this magnitude result in significantly lower values for the O2(+) concentration than those measured on AE-C over the altitude range to 160 to 200 km, because of the removal process O2(+) + N k3 yields NO(+) + O. The discrepancy can be explained in terms of latitudinal variations in both the N and O2 densities. Evidence is presented which indicates that k3 could be as low as 0.1 billionth per cu cm at ionospheric temperatures. K3 is the rate constant for the reaction of O2(+) with N(4-S).