Soot and hydrocarbon formation in a turbulent diffusion flame

Formation and emission of soot and polycyclic aromatic hydrocarbons (PCAH) from a turbulent continuous flow combustor have been studied. Measurements included mass concentration of both soot and PCAH, composition of individual PCAH, and size distribution of soot particles, as a function of mixing intensity, fuel equivalence ratio and type of fuel (kerosene or benzene). Both soot and PCAH concentrations reach maxima early in the flame, after which PCAH decays rapidly and soot decays much slower. The maximum PCAH concentration always preceded that of soot in agreement with the concept that certain PCAH may serve as intermediates in soot formation. An approximate calculation based on the assumptions of local equilibrium with respect to soot formation and a Gaussian distribution of air-fuel mixedness gave satisfactory correlations of the data on soot formation at the higher cold gas velocity. At the lower velocity, the amount of soot and PCAH formed was drastically increased and strongly dependent on fuel atomization.