Nitramine smokeless propellant research

A transient ballistics and combustion model was derived to represent the closed vessel experiment that is widely used to characterize propellants. The model incorporates the nitramine combustion mechanisms. A computer program was developed to solve the time dependent equations, and was applied to explain aspects of closed vessel behavior. It is found that the rate of pressurization in the closed vessel is insufficient at pressures of interest to augment the burning rate by time dependent processes. Series of T-burner experiments were performed to compare the combustion instability characteristics of nitramine (HMX) containing propellants and ammonium perchlorate (AP) propellants. It is found that the inclusion of HMX consistently renders the propellant more stable.