Time-resolved double-probe study in a He-Hg afterglow plasma

An experimental double-probe technique is described which allows the He(+) ion density to be measured directly as a function of time in the afterglow of a helium-metal-vapor discharge. As an application example, two CW laser transitions of the He-Hg(+) laser at 6150 and 7944 A are considered which both arise from excited 7p (2) P terms of Hg II. The time-resolved double-probe technique is used to measure the destruction rate of the He(+) ion density, which is then compared with the spontaneous-emission decay rate for 7p (2) P terms of Hg II. The results obtained show unambiguously and directly that the dominant excitation process for the two transitions considered is a charge-transfer collisional reaction of the form He(+) plus Hg yields He plus metastable Hg(+) plus the energy defect for this reaction. It is noted that the time-resolved double-probe technique may provide a simple method for measuring ion mobilities in a multi-ion plasma.