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Process for the preparation of calcium superoxideCalcium superoxide is prepared in high yields by spreading a quantity of calcium peroxide diperoxyhydrate on the surface of a container, positioning said container in a vacuum chamber on a support structure through which a coolant fluid can be circulated, partially evacuating said vacuum chamber, allowing the temperature of the diperoxyhydrate to reach the range of about 0 to about 40 C; maintaining the temperature selected for a period of time sufficient to complete the disproproriation of the diperoxyhydrate to calcium superoxide, calcium hydroxide, oxygen, and water; constantly and systematically removing the water as it is formed by sweeping the reacting material with a current of dry inert gas and/or by condensation of said water on a cold surface; backfilling the chamber with a dry inert gas; and finally, recovering the calcium superoxide produced.
Document ID
19790001991
Acquisition Source
Legacy CDMS
Document Type
Other - Patent
Authors
Ballou, E. V.
(San Jose State Univ. Calif., United States)
Wood, P. C.
(San Jose State Univ. Calif., United States)
Wydeven, T. J.
(NASA Ames Research Center Moffett Field, CA, United States)
Spitze, L. A.
(San Jose State Univ. Calif., United States)
Date Acquired
September 3, 2013
Publication Date
July 18, 1978
Subject Category
Inorganic And Physical Chemistry
Report/Patent Number
Patent Application Number: US-PATENT-APPL-SN-814378
Patent Number: NASA-CASE-ARC-11053-1
Patent Number: US-PATENT-4,101,644
Accession Number
79N10162
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.
Patent
NASA-CASE-ARC-11053-1|US-PATENT-4,101,644
Patent Application
US-PATENT-APPL-SN-814378
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