Determination of trace gases in learjet and U-2 whole air samples collected during the intertropical convergence zone experiment

The contribution of Washington State University (WSU) to the Intertropical Convergence Zone (ITCZ) study, conducted in the Panama Canal Zone in July 1977 is reported. The ITCZ program had the objective to study the meteorology and air chemistry to determine, if possible, the magnitude of injection of tropospheric air into the stratosphere in the ITCZ. WSU was responsible for two phases of the air chemistry program for the ITCZ study: (1) the collection of whole-air samples from ground level to 13.7 km using a Learjet as a sampling platform, and the analysis of the samples for selected halocarbons, C2 hydrocarbons, N2O, and SF6; and (2) the analysis for selected halocarbon species and N2O of low pressure whole-air samples, collected between 13.7 km and 21.3 km by a U-2 aircraft. The report is divided into separate sections describing the Learjet and the U-2 sampling methods, analytical methods, and results. Complete data tables for all samples analyzed are given.