Ultraviolet spectroscopy of comets

Results of observations of comets in the ultraviolet are reviewed in relation to their significance for the chemistry and physics of the cometary coma and the composition of the cometary ice. Ultraviolet cometary observations began in 1970, when a hydrogen envelope was discovered extending millions of kilometers from the nucleus of comet Bennett, and continued with the discovery of oxygen and carbon in comet Kohoutek and the acquisition of comprehensive UV spectra from comets West (1976 VI), Seargent (1978 XV) and Bradfield (1979 X). The available cometary spectra are remarkably similar, indicative of a common composition and origin for comets and the insignificance of chemical reactions in the inner coma to species abundances. Ultraviolet spectroscopy has also allowed the determination of gas production rates from either the surface brightness or the total luminosity in a given spectral line. IUE observations of comet Bradfield reveal the water production rate to vary as the -3.7 power of heliocentric distance from 0.71 to 1.55 AU, incompatible with solar energy input as the controlling influence on water vaporization.