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Thermal cis-trans isomerization of cis,cis-3,7-decadiene - A model for cis-1,4-polybutadieneThe thermal cis-trans isomerization of cis,cis-3,7-decadiene (DD), a model compound for cis-PBD, is reported. It is demonstrated that the rather low E for the polyalkenamer isomerizations compared with that for the 2-olefins is not an artifact of the solid polymer structures, but rather is characteristic of both small and large molecules possessing pairs of nonconjugated vinylene double bonds in a suitable arrangement.
Document ID
19840048817
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Golub, M. A.
(NASA Ames Research Center Moffett Field, CA, United States)
Lee, W. M.
(NASA Ames Research Center Moffett Field, CA, United States)
Date Acquired
August 12, 2013
Publication Date
January 1, 1983
Publication Information
Publication: Journal of Polymer Science: Polymer Letters Edition
Volume: 21
ISSN: 0360-6384
Subject Category
Chemistry And Materials (General)
Report/Patent Number
ISSN: 0360-6384
Accession Number
84A31604
Distribution Limits
Public
Copyright
Other

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