Detection of interstellar CCD

The first detection of interstellar CCD has been obtained in the N = 3-2, J = 7/2-5/2 line at 216.3732 GHz towards the Kleinman-Low nebula. An abundance ratio CCD/CCH of 0.045 is found, indicating in this molecule a deuterium enhancement similar to that found for HNC, but an order of magnitude higher than for HCN. Negative results towards DR 21(OH), NGC 2264, L 134N, TM Cl, Rho OphB2, and IRC 10216 rule out a stronger D enhancement for CCD than for other deuterated molecules in these sources. Predictions of currently developed ion-molecule reaction schemes are consistent with the CCD line detected and the negative results.