The NO-NO2 system at laboratory surfaces

Experiments on formation and excitation of NO2 and NO molecules at (and near) laboratory surfaces of varying degrees of characterization are reviewed. On some transition metals NO is desorbed in the B sub 2 pi state, from which it radiates the familiar beta (B yields x) bands. In contrast while an ONO intermediate is inferred from isotope interchange measurements on platinum, neither ground state nor excited NO2 has been found to be desorbed under the relatively limited number of laboratory conditions so far investigated.