Bidirectional reflectance spectroscopy. IV - The extinction coefficient and the opposition effect

An analytical model is developed for the opposition effect (heiligenshein) in the case of light scattering from a semi-infinite, particulate medium with particles that are large relative to the wavelength. The effect is common for natural materials, and comprises a brightness surge in light diffusively reflected from a surface at near zero phase. A generalized expression is devised for the extinction coefficient of a particulate medium. Models are developed for step function and hyperbolic tangent distributions of light scattered from a stratified medium and exhibiting the opposition effect. A maximum brightness amplitude increase of 0.753 is projected for the effect. Greater values must have other causes.