Determination of spectroscopic properties of atmospheric molecules from high resolution vacuum ultraviolet cross section and wavelength measurements

Progress is given on work on: cross section measurements in the transmission window regions of the Schumann-Runge bands of oxygen; the determinations of predissociation linewidths; the theoretical calculation of band oscillator strengths of the Schumann-Runge absorption bands of O-16O-18; the determination of molecular spectroscopic constants; and the combined Herzberg continuum cross sections. The experimental investigations relevant to the cross section measurements, predissociation linewidths, and molecular spectroscopic constants are effected at high resolution with a 6.65 m scanning spectrometer which is, by virtue of its small instrumental width (FWHM = 0.0013 nm), suitable for cross section measurements of molecular bands with discrete rotational structure. Such measurements are needed for accurate calculations of the stratospheric production of atomic oxygen and heavy ozone formed following the photo-predissociation of O-16O-18 by solar radiation penetrating between the absorption lines of O-16(sub 2).