HDO in the Martian atmosphere - Implications for the abundance of crustal water

A one-dimensional photochemical model is presently used to ascertain the nature of those chemical and physical processes of the Martian atmosphere responsible for the preferential escape of hydrogen over deuterium. A comparison of the present theoretical considerations with recent HDO observations indicates that Mars contains 0.2 m of (globally averaged) crustal water that is exchangeable with the atmosphere. This estimate, which is substantially lower than those obtained for Martian subsurface water on the basis of Viking image-derived geomorphological analyses, can be reconciled only if a small fration of the crustal water is exchangeable with the atmosphere.