Evaluation of materials for tunable vibronic lasers

Three techniques (peak single-pass gain, fluoresence band narrowing, and lifetime shortening) for determining the effects of stimulated emission on the spectra of solid-state vibronic laser materials have been compared. The methods were employed to determine the pump energy density and population inversion at threshold, the stimulated emission cross section, and the gain coefficient for two potential vibronic laser materials. An effective shortening of the fluorescence lifetime is predicted at high excitation levels, with a distinct threshold where stimulated emission processes become important.