Shock waves in mixtures - A re-examination

The structure of normal shock waves in binary mixtures is analyzed, using Monte Carlo direct simulation, and compared with previous experimental data. Previous work by Erwin et al. used a collision method based directly on the intermolecular potential function; the present work extends this approach to binary mixtures, obtaining heteromolecular collision cross sections from the corresponding potentials. Results are presented for helium-argon mixtures, with conditions corresponding to the experiments of Harnett and Muntz (1972).