Electron collision cross sections involving excited states

The vibrational excitation/deexcitation of vibrationally and rotationally hot N2 by electron impact, pertinent to the reactions in the flow field around a hypersonic space vehicle entering the planetary atmosphere, is calculatively investigated. It is found that the resonance position shifts to a lower energy when N2 is rotationally hot. Electron impact excitations between electronic excited states of N2 are studied using a multichannel treatment. The results show that the assumption that excited-excited cross sections are the same as ground-excited ones, and result in the same final state, is invalid. A more reliable set of data on N2 is provided.