Measurements of lower tropospheric ozone at mid-latitudes of the Northern and Southern Hemisphere

Ground-based measurements of ozone have been carried out at three stations in the German alps (47 deg N, 11 deg E, altitudes 740, 1776, and 2962 m a.s.l.) as well as at the coastal station Cape Point (34 deg S, 18 deg E). For the mountain sites (at 1776 and 2962 m), trend calculations based on monthly means have yielded O3 growth rates of 0.8 and 0.9 ppbv yr(exp -1), respectively, over the period 1978-91. Seasonally differentiated data sets have yielded higher rates for summer than for winter. The impact of near-ground photochemical O3 production on the observed O3 concentration is shown. No significant long-term O3 trend has been observed at 740 m (valley floor) as well as at the southern hemispheric station Cape Point. Evidence exists for a close relationship between the amplitude variations of the annual cycles of O3 and CO at Cape Point.