The updated statistical inversion technique to the evaluation of Umkehr observations

In the present study the standard retrieval Umkehr method to estimate the vertical distribution of ozone was updated using a statistical approach to the mathematical inversion scheme. The vertical ozone profile covariance matrix was used as a priori information for the inverse problem. A new method of the ozonesonde data organization according to air mass types helped to improve the covariance matrix quality. A retrieval method was developed using eigenvector technique. An optimal vertical ozone profile resolution was determined from the mathematical inversion scheme analysis based on the same technique. The sun radiation transfer was accounted for multiple scattering and atmospheric sphericity in this calculation. The retrievals using actual Umkehr Dobson spectrophotometer observations were also performed to provide the comparison of the standard and updated methods with concurrent ozone sound data at Boulder U.S. The comparison has revealed that the present method has some advantages in both resolution and accuracy, as compared to the standard one, especially for the atmospheric layers below ozone maximum.