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Mesospheric ozone measurements by SAGE IISAGE II observations of ozone at sunrise and sunset (solar zenith angle = 90 deg) at approximately the same tropical latitude and on the same day exhibit larger concentrations at sunrise than at sunset between 55 and 65 km. Because of the rapid conversion between atomic oxygen and ozone, the onion-peeling scheme used in SAGE II retrievals, which is based on an assumption of constant ozone, is invalid. A one-dimensional photochemical model is used to simulate the diurnal variation of ozone particularly within the solar zenith angle of 80 deg - 100 deg. This model indicates that the retrieved SAGE II sunrise and sunset ozone values are both overestimated. The Chapman reactions produce an adequate simulation of the ozone sunrise/sunset ratio only below 60 km, while above 60 km this ratio is highly affected by the odd oxygen loss due to odd hydrogen reactions, particularly OH. The SAGE II ozone measurements are in excellent agreement with model results to which an onion peeling procedure is applied. The SAGE II ozone observations provide information on the mesospheric chemistry not only through the ozone profile averages but also from the sunrise/sunset ratio.
Document ID
Document Type
Conference Paper
Chu, D. A. (G and A Technical Software, Inc. Hampton, VA, United States)
Cunnold, D. M. (G and A Technical Software, Inc. Hampton, VA, United States)
Date Acquired
September 6, 2013
Publication Date
April 1, 1994
Publication Information
Publication: NASA. Goddard Space Flight Center, Ozone in the Troposphere and Stratosphere, Part 2
Subject Category
Distribution Limits
Work of the US Gov. Public Use Permitted.

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IDRelationTitle19950004531Analytic PrimaryWorkshop on the Analysis of Interplanetary Dust Particles