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Incorporation of New Benzofulvene Derivatives Into Polymers to Give New NLO MaterialsThe need for fast electro-optic switches and modulators for optical communication, and laser frequency conversion has created a demand for new second-order non-linear optical materials. One approach to produce such materials is to align chromophores with large molecular hyperpolarizabilities in polymers. Recently fulvenes and benzofulvenes which contain electron donating groups have been shown to exhibit large second-order non-linear optical properties. The resonance structures shown below suggest that intramolecular charge transfer (ICT) should be favorable in omega - (hydroxyphenyl)benzofulvenes and even more favorable in omega-omega - (phenoxy)benzofulvenes because of the enhanced donor properties of the O group. This ICT should lead to enormously enhanced second-order hyperpolarizability. We have prepared all three new omega - (hydroxyphenyl)benzofulvenes by the condensation of indene with the appropriate hydroxyaryl aldehyde in MeOH or MeOH/H2O under base catalysis. In a similar fashion we have prepared substituted benzofulvenes with multipal donor groups. Preliminary studies show that some of our benzofulvene derivatives exhibit second order harmonic generation (SHG). Measurements were carried out by preparing host-guest polymers. The results of our work on benzofulvene derivatives in host-guest polymers when covalently bonded in the polymer will be described.
Document ID
19960047700
Acquisition Source
Langley Research Center
Document Type
Conference Paper
Authors
Bowens, Andrea D.
(Clark-Atlanta Univ. GA United States)
Bu, Xiu
(Clark-Atlanta Univ. GA United States)
Mintz, Eric A.
(Clark-Atlanta Univ. GA United States)
Zhang, Yue
(Laser Photonics Technology, Inc. Amherst, NY United States)
Date Acquired
August 17, 2013
Publication Date
March 1, 1996
Publication Information
Publication: Proceedings of the 4th Annual Workshop: Advances in Smart Materials for Aerospace Applications
Subject Category
Nonmetallic Materials
Accession Number
96N33310
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.
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