Accurate Energetics for the Unimolecular Decomposition of HN2

We report internally contracted configuration interaction (ICCI) calculations along the constrained energy minimum (CEM) path for the addition of H to N2 with both CC-pVQZ and augmented CC-pVQZ basis sets. The results agree to within 0.5 kcal/mol with the larger basis set results of Walch, which were used to calibrate the HN2 potential energy surface used by Koizumi, Schatz, and Walch in coupled channel calculations to determine the lifetimes for unimolecular decay of the lowest vibrational levels of HN2. These small changes in the potential energy surface should have no significant effect on the computed lifetimes.