Composite Properties of Polyimide Resins Made From "Salt-Like" Solution Precursors

Recent work in high temperature materials at NASA Langley Research Center (LaRC) have led to the development of new polyimide resin systems with very attractive properties. The majority of the work done with these resin systems has concentrated on determining engineering mechanical properties of composites prepared from a poly(amide acid) precursor.

Three NASA Langley-developed polyimide matrix resins, LaRC-IA, LaRC-IAX, and LaRC-8515, were produced via a "salt-like" process developed by Unitika Ltd. The "salt-like" solutions (sixty-five percent solids in NMP) were prepregged onto Hexcel IM7 carbon fiber using the NASA LaRC Multipurpose Tape Machine. Process parameters were determined and composite panels fabricated. Mechanical properties are presented for these three intermediate modulus carbon fiber/polyimide matrix composites and compared to existing data on the same polyimide resin systems and IM7 carbon fiber manufactured via poly(amide acid) solutions (thirty-five percent solids in NMP). This work studies the effects of varying the synthetic route on the processing and mechanical properties of polyimide composites.