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Nickel cobalt phosphorous low stress electroplatingAn electrolytic plating process is provided for electrodepositing a nickel or nickel cobalt alloy which contains at least about 2% to 25% by atomic volume of phosphorous. The process solutions contains nickel and optionally cobalt sulfate, hypophosphorous acid or a salt thereof, boric acid or a salt thereof, a monodentate organic acid or a salt thereof, and a multidentate organic acid or a salt thereof. The pH of the plating bath is from about 3.0 to about 4.5. An electroplating process is also provided which includes electroplating from the bath a nickel or nickel cobalt phosphorous alloy. This process can achieve a deposit with high microyield of at least about 84 kg/mm.sup.2 (120 ksi) and a density lower than pure nickel of about 8.0 gm/cc. This process can be used to plate a deposit of essentially zero stress at plating temperatures from ambient to 70.degree. C.
Document ID
20080004990
Acquisition Source
Marshall Space Flight Center
Document Type
Other - Patent
Authors
Engelhaupt, Darell E.
Ramsey, Brian D.
Date Acquired
August 24, 2013
Publication Date
June 18, 2002
Subject Category
Mechanical Engineering
Report/Patent Number
Patent Application Number: US-PATENT-APPL-SN-456862
Patent Number: US-PATENT-6,406,611
Funding Number(s)
CONTRACT_GRANT: NCC8-65
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.
Patent
US-PATENT-6,406,611
Patent Application
US-PATENT-APPL-SN-456862
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