The Evolution of Hydrocarbons in Saturn's Northern Storm Region

The massive storm at 40N on Saturn that began in December 2010 has produced significant and lasting effects in the northern hemisphere on temperature and species abundances (Fletcher et aL 2011). The northern storm region was observed on several occasions between March 2011 and April 2012 by Cassini's Composite Infrared Spectrometer (CIRS) at a spectral resolution (0.5/cm) which permits the study of trace species in Saturn's stratosphere. During this time period, stratospheric temperatures in regions referred to as "beacons" (warm regions at specific longitudes at the latitude of the storm) became significantly warmer than pre-storm values of 140K, peaking near 220K, and subsequently cooling. These warm temperatures led to greatly enhanced infrared emission due to C4H2, C3H4, C2H2, and C2H6 in the stratosphere as well as the first detection of C2H4 on Saturn in the thermal infrared (Hesman et al. 2012). Using CH4 as a thermometer of Saturn's stratosphere in the beacon regions, we can derive the mixing ratios of each of these molecules. The most common hydrocarbons (C2H2 and C2H6) serve as dynamical tracers on Saturn and their abundances may constrain vertical motion in the stratosphere. All of these hydrocarbons are products of methane photolysis. Since many of the photochemical reactions that produce heavier hydrocarbons such as C4H2 and C3H4 are temperature sensitive, the beacon region provides a natural laboratory for studying these reactions on Saturn. We will discuss the time evolution of the abundances of each of these hydrocarbons from their pre-storm values, through the period of maximum heating , and during the period of cooling that is taking place in Saturn's stratosphere.