Near-Infrared Reflectance Spectroscopy of Venus-Analog Rocks at Venus Surface Temperatures

Venus’ surface can be viewed in emission through the relatively opaque atmosphere via a few spectral ‘windows’ in the near-infrared (NIR, most near 1 μm). Venus’ surface appears to show emissivities that correlate with surface geology, and these emissivity variations are interpreted as differences in surface rock type (mafic vs. silicic) and/or extent of weathering (Fe(2+) silicates vs. Fe(3+)-oxide-coated). To understand and quantify the observed variations in NIR emissivity, laboratories are measuring high-T NIR emissivity directly. For example, the measured emissivities of basalts in the wavelength range 0.85 – 1.2 μm are ~0.9. This value can be tested by measurement of reflectance, because Kirchoff’s Law holds that emissivity (e) = 1 – reflectance (r). The r of basalt in the NIR is ~0.1 so its e should be ~0.9. However, high-T NIR e’s of silicic igneous rocks (granitic, rhyolite) are reported to be 0.8-0.9, which is inconsistent with r values of 0.3-0.7 of such rocks at room-T. For both datasets to be correct, the r values of silicic igneous rock would have to decrease precipitously between room and Venus surface temperatures. This seems unlikely.