Developments in Fullerene Ion Propulsion Research

Several reports of successful operation of DC discharges using fullerene vapor have been made. However, degradation of the propellant molecules in the vapor source and in contact with the filament cathode was observed in each case. Because disintegration of the fullerene cage could result in poor performance or thruster failure, we have developed an RF ion thruster for use with C60 propellant to avoid the presence of electrodes inside the discharge chamber. Also, we conducted a series of experiments to ascertain the stability of fullerenes at high temperatures. We find that when C60 and C70 are maintained at temperatures above 1073 K, or are exposed to hot metal surfaces, significant degradation occurs. We find an activation energy of 261.5 kJ/mol for this process. At temperatures below 873 K, no breakdown of fullerenes can be detected, even after heating for 6 hours. The effect of these findings on C60 ion thruster design is discussed.