Surfactant Studies for Bench Scale Operation

A study has been carried out to examine the effect of a surfactant, sodium lignosulfonate, on the coal liquefaction process to increase coal conversions. A series of coal liquefaction experiments with surfactant addition were conducted in a stirred batch autoclave with 1:2 coal-solvent mixtures with Illinois #6 coal at temperatures from 300 to 400 degrees C and hydrogen pressures from 1500 to 1800 psig. The treated products were analyzed for overall conversion and the distribution of the converted products into lighter and heavy oil fractions, respectively. The batch autoclave results indicate an increase in coal conversions due to surfactant addition at all processing conditions. The analysis also indicates an upgrading of the product slate for temperatures not exceeding 350 degrees C...