Relative Detectability of Iron-Bearing Phases for the Mars 2020 Sherloc Deep UV Raman Instrument: 1. Focusing on Carbonates

A deep ultraviolet (DUV) Raman and fluorescence instrument is a surface standoff instrument mounted on the robotic arm of the Mars 2020 (M2020) rover Perseverance, and it is a key element of the Scanning Habitable Environments with Luminescence for Organics and Chemicals (SHERLOC) investigation [1]. Measurement and science objectives include mineralogical and organic images (~100 μm/pixel) that map sub-millimeter spatial distributions and characterization of primary and secondary minerals, potential organics, and their interaction/alteration products. The results of data analysis pertain to understanding igneous and alteration processes on Mars through time, assessing habitability, evidencing in situ biosignatures, and, along with results from other Perseverance instruments, selecting samples to cache for Mars sample return. Acceptance of the SHERLOC investigation for the NASA M2020 mission [2] created a need for Mars-relevant DUV Raman spectra, particularly for inorganic materials [e.g., 3, 4]. As reported previously [e.g., 4, 5], phases with Fe cations as essential elements (e.g., siderite (FeCO3) and ankerite (FeCa(CO3)2) for carbonates) significantly hinder detection by DUV Raman because of intense absorption of incident and scattered DUV laser radiation by Fe cations. We report here the relative detectability of carbonates (Mg,Ca,Fe,Mn)CO3 by DUV Raman using a SHERLOC analog laboratory instrument.