Noise Reduction for Solar-Induced Fluorescence Retrievals Using Machine Learning and Principal Component Analysis: Simulations and Applications to GOME-2 Satellite Retrievals

We use a spectral-based approach that employs principal component analysis along with a relatively shallow artificial neural network (NN) to substantially reduce noise and other artifacts in terrestrial chlorophyll solar-induced fluorescence (SIF) retrievals. SIF is a very small emission at red and far-red wavelengths that is difficult to measure and is highly sensitive to random errors and systematic artifacts. Our approach relies upon an assumption that a trained NN can effectively reconstruct the total SIF signal from a relatively small number of leading principal components of the satellite-observed far-red radiance spectra without using information from the trailing modes that contain most of the random errors. We test the approach with simulated reflectance spectra produced with a full atmospheric and surface radiative transfer model using different observing and geophysical parameters and various noise levels. Resulting noisy and noise-reduced retrieved SIF values are compared with true values to assess performance. We then apply our noise reduction approach to SIF derived from two different satellite spectrometers. For evaluation, since the truth in this case is unknown, we compare SIF retrievals from two independent sensors with each other. We also compare the noise-reduced SIF temporal variations with those from an independent gross primary product (GPP) product that should display similar variations. Results show that our noise reduction approach improves capture of SIF seasonal and inter-annual variability. Our approach should be applicable to many noisy data products derived from spectral measurements. Our methodology does not replace the original retrieval algorithms; rather the original noisy retrievals are needed as the target for the NN training process.