Kinetics of O/super 3P/ + CO + M recombination.

Measurement of rate coefficients over the temperature range from 250 to 370 K for the three-body recombination of O(super 3P) with CO. Earlier results at 300 K have been re-evaluated and were found to have been influenced by unknown impurities in the CO, which have now been removed by more elaborate purification methods. For CO as the third body, the rate constant is given by K = 6.5 x 10 to the minus 33rd exp (-4340 plus or minus 550/RT) cm to the 6th power per sq molecule per sec. For N2 and CO2, the 296 K rate constants are 2.3 and 6.2 x 10 to the minus 36th cm to the 6th power per sq molecule per sec, respectively.