Non-gassing nickel-cadmium battery electrodes and cells: Testing of 25 Ah cells

The testing of 30 practical size, experimental 25 ampere hour cells constructed as part of an earlier negative limited cell development program is discussed. The test results showed that the negative limited cell is a possible means of developing a long-lived secondary cell. The cells were tested for 500 cycles using an accelerated regime approximating a 90-minute orbit period. Three groups of ten cells were tested at 0,25, and 40 C. The cycle data showed that the negative limited cells had higher degradation rates at the higher operating temperatures. At the conclusion of 500 cycles, the three groups had average capacities of 16.83, 12.74, and 5.71 ampere hours for testing at 0, 25, 40 C, respectively. The conditioning capacities of these cells was in the 25 ampere hours range. The internal cell pressures of the three groups was also temperature dependent and was, in general, in the 2 psig range during the course of the test program. No periodic variation of the internal pressure with the state-of-charge was observed except with some cells tested at 40 C.