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Equilibrium properties of a one-dimensional kinetic system.One-dimensional systems of N = 500 and 250 particles in equilibrium are numerically simulated utilizing the method of molecular dynamics. Periodic boundary conditions are imposed. The classical two-body interaction potential is short range, repulsive and has a corresponding finite force. The equations of state are determined for densities both less and greater than one. Corresponding theoretical isochores are determined from models based on nearest-neighbor interactions and on a truncated virial expansion, and a comparison is made with the experimental isochores. Time independent radial distributions are constructed numerically and discussed. A change of state from a solidlike state to a fluid-gas state based on the penetrability of the particles is predicted. The transition temperatures are estimated from the radial distribution functions and the nearest-neighbor model. Self-diffusion is observed and the corresponding constants are determined from the velocity autocorrelation functions.
Document ID
19730053097
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Williams, J. H.
Joyce, G.
(Iowa, University Iowa City, Iowa, United States)
Date Acquired
August 7, 2013
Publication Date
July 15, 1973
Publication Information
Publication: Journal of Chemical Physics
Volume: 59
Subject Category
Physics, Atomic, Molecular, And Nuclear
Accession Number
73A37899
Funding Number(s)
CONTRACT_GRANT: NGL-16-001-043
CONTRACT_GRANT: AT(11-1)-2059
CONTRACT_GRANT: NSF GA-31676
Distribution Limits
Public
Copyright
Other

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