Polar volatiles on Mars - Theory versus observation

Synthesis of the results of the Mariner 9 mission, as they pertain to polar volatiles, and comparison of them with a description of the solid-vapor equilibrium relations believed to be presently active on Mars. The discovery by Mariner 9 of extensive volcanic deposits on portions of the Martian surface suggests that the total amount of CO2 liberated to the surface probably exceeds that now present in the atmosphere. Thus excess CO2 in the solid form is to be expected in the polar areas. Although the simplified model of Leighton and Murray (1966), which predicts a permanent CO2 cap, has significant deficiencies both theoretically and observationally, the seasonal caps are composed of CO2, as predicted, excess CO2 is quite likely, and a permanent deposit of solid CO2 evidently is in equilibrium with atmospheric CO2. It is suggested that there must be a large reservoir of solid CO2 in gaseous equilibrium with the atmosphere, but buried immediately below the exposed residual water-ice cap. This reservoir is believed to be located near the north pole. The principal effect of such a reservoir is to average out annual and longer-term fluctuations in the polar heat balance.