Cooling histories of lunar rocks based on opaque mineral geothermometers

The application of experimentally derived data on (1) the Zr partitioning between coexisting ilmenite and ulvospinel and (2) the Ti partitioning between coexisting troilite and ilmenite has allowed the discernment of differences in subsolidus cooling histories of lunar rocks - e.g., the Apollo 15 Type I Mare basalts. The rocks which show Zr partitionings reequilibrated to lower temperature (i.e., below 950 C), as a result of slow cooling, also show evidence for subsolidus reduction of ulvospinel to ilmenite + native Fe. It is suggested that the presence of ulvospinel reduction is not evidence a priori that these rocks have undergone more reducing conditions than the other Apollo 15 Mare basalts; it may only indicate that the cooling rates were slower in that subsolidus temperature range (i.e., much less than 900 C) where oxygen fugacity values were favorable for ulvospinel reduction. The rocks with higher temperature Zr partitionings and no ulvospinel reduction may have cooled under the same fugacity conditions but at a faster rate.