Infrared pumping processes for SiO masers

The J = 2 to 1 transition of the first excited vibrational state (v = 1) Si(28)O(16) has recently been shown to produce maser amplification near 86,245 MHz in Orion A and in several stars. Two possible pumping mechanisms are proposed for such masers. One involves the near coincidence between the frequencies of the 1-0 (RO) and 3-2 (R18) transitions in Si(28)O(16). The other requires emission by SiO and reabsorption without the necessity for an accidental frequency coincidence. Each of these types of mechanisms may occur for other transitions of molecules in a medium illuminated by intense infrared radiation, or with strong temperature gradients.