Rate of recombination of oxygen atoms and CO at temperatures below ambient

The measurements reported were conducted with 30.0 torr CO, 40.0 torr argon, and varying amounts of carbon dioxide from about 20 to 230 torr. Measurements were made at 277, 272, 263, and 257 K. The pseudo-first-order decay rate as a function of carbon dioxide pressure is shown in a graph. An Arrhenius plot for the rate constants obtained from the measurements is also presented. A value for the activation energy was determined on the basis of a linear least-squares fit to the data.