Canonical fluid thermodynamicsThe space-time integral of the thermodynamic pressure plays in a certain sense the role of the thermodynamic potential for compressible adiabatic flow. The stability criterion can be converted into a variational minimum principle by requiring the molar free-enthalpy and temperature to be generalized velocities. In the fluid context, the definition of proper-time differentiation involves the fluid velocity expressed in terms of three particle identity parameters. The pressure function is then converted into a functional which is the Lagrangian density of the variational principle. Being also a minimum principle, the variational principle provides a means for comparing the relative stability of different flows. For boundary conditions with a high degree of symmetry, as in the case of a uniformly expanding spherical gas box, the most stable flow is a rectilinear flow for which the world-trajectory of each particle is a straight line. Since the behavior of the interior of a freely expanding cosmic cloud may be expected to be similar to that of the fluid in the spherical box of gas, this suggests that the cosmic principle is a consequence of the laws of thermodynamics, rather than just an ad hoc postulate.
Document ID
19750049750
Acquisition Source
Legacy CDMS
Document Type
Other - Collected Works
Authors
Schmid, L. A. (NASA Goddard Space Flight Center Theoretical Studies Branch, Greenbelt, Md., United States)