Non-thermal 10 micrometers CO2 emission lines in the atmospheres of Mars and Venus

Mechanisms for the excitation of strong 10 micrometer CO2 emission lines seen on Mars and Venus are examined. Line absorption of near IR solar flux directly by CO2 or by H2O with collisional transfer of energy to CO2 are proposed as likely excitation mechanisms. Altitudes for peak 10 micrometer emission are estimated to be near 80 km for Mars and 120 km for Venus.