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X-ray powder diffraction study of poly/carbon monofluoride/, CF/1.12/Data from X-ray diffraction studies of the poly(carbon monofluoride) with empirical formula CF(1.09-1.15) are reported, and possible intercalation arrangements for the substance are discussed. The data do not conform to true hexagonal symmetry, indicating that the carbon atoms are not coplanar. Each bond angle of carbon is 118.8 deg, and the carbon-carbon distance is 1.47 A. The interlayer distance is 5.76 A. A total absence of (hkl) reflections in the X-ray pattern shows that the separate CF layers are not regularly arranged with respect to one another.
Document ID
19760038824
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Mahajan, V. K.
(Rice Univ. Houston, TX, United States)
Badachhape, R. B.
(Rice Univ. Houston, TX, United States)
Margrave, J. L.
(Rice University Houston, Tex., United States)
Date Acquired
August 8, 2013
Publication Date
January 1, 1974
Publication Information
Publication: Inorganic and Nuclear Chemistry Letters
Volume: 10
Issue: 12, 1
Subject Category
Inorganic And Physical Chemistry
Accession Number
76A21790
Funding Number(s)
CONTRACT_GRANT: NGR-44-006-001
Distribution Limits
Public
Copyright
Other

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