Diode laser spectra of CC12F2 near 10.8 microns; air-broadening effects

A tunable diode laser absorption spectrometer with resolution of about 0.0001/cm was used to record air-broadened spectra of CC12F2 in two regions near 922.8/cm and 921.7/cm. In the 922.8/cm region the structure shows good intensity contrast at pressures corresponding to upper atmospheric pressures. The absorption features have a spacing of 0.014/cm, which is sufficiently wide to retain spectral structure at pressures as high as 48 torr or altitudes as low as 19 km. The apparent broadening is 2 MHz/torr. The single-line broadening coefficient for CC12F2 can be estimated to be 8 + or - 2 MHz/torr FWHM. In the 921.7/cm region the high-resolution structure is discernible up to 24 torr, but the intensity contrast is not sufficiently strong to be of use in analysis of stratospheric spectra.