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A new channel for the formation of hydrogen cyanide in CH2-N2 systemsThe reaction between N2 and either the singlet or the triplet electronic state of CH2 is investigated in order to shed light on the formation of NO in fuel-rich hydrocarbon flames. For the reaction of N2 and the triplet CH2, a rate constant less than or equal to 10 to the minus 16th power cu cm/molecule-sec is obtained. The time history of hydrogen cyanide production from the CH2-N2 systems is discussed as a basis for understanding the possible reaction routes from HCN to NO.
Document ID
19780053865
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Laufer, A. H.
(National Bureau of Standards Washington, DC, United States)
Bass, A. M.
(National Bureau of Standards, Institute for Materials Research, Washington D.C., United States)
Date Acquired
August 9, 2013
Publication Date
June 1, 1978
Publication Information
Publication: Combustion and Flame
Volume: 32
Subject Category
Inorganic And Physical Chemistry
Accession Number
78A37774
Distribution Limits
Public
Copyright
Other

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