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The rate constant for the reaction of oxygen /3P/ atoms with dichlorine monoxideA fast flow discharge apparatus was used to measure the rate constant for the reaction of ground state oxygen atoms with dichlorine monoxide in the temperature range 236-295 K. The air afterflow technique (NO2 chemiluminescence) was used for detection of oxygen atoms. The Arrhenius expression for the rate constant was found to be 2.7 plus or minus 0.3 times 10 to the -11th power exp(-560 plus or minus 80/T) cu cm per molecule per sec. At 295 K the rate constant is 4.1 plus or minus 0.5 times 10 to the -12th power cu cm per molecule per sec.
Document ID
19780063940
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Miziolek, A. W.
(California, University Irvine, Calif., United States)
Molina, M. J.
(California Univ. Irvine, CA, United States)
Date Acquired
August 9, 2013
Publication Date
August 10, 1978
Publication Information
Publication: Journal of Physical Chemistry
Volume: 82
Subject Category
Inorganic And Physical Chemistry
Accession Number
78A47849
Funding Number(s)
CONTRACT_GRANT: NSG-7208
Distribution Limits
Public
Copyright
Other

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