Pyroxene-melt equilibria

A thermodynamic analysis of pyroxene-melt equilibria is performed through use of a literature survey of analyses of high-Ca pyroxene and coexisting silicate melt pairs and analyses of low-Ca pyroxene silicate melt pairs. Reference is made to a modified version of a model developed by Bottinga and Weill (1972) which more successfully accounts for variations in melt composition than does a model which considers the melt to be composed of simple oxides which mix ideally. By using a variety of pyroxene melt relations, several pyroxene-melt and low-Ca pyroxene-high-Ca pyroxene geothermometers are developed which have internally consistant precisions of approximately + or - 20 C. Finally, it is noted that these equations may have application in modeling the evolution of mineral compositions during differentiation of basaltic magmas.