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Unimolecular decomposition reactions at low-pressure: A comparison of competitive methodsThe lack of a simple rate coefficient expression to describe the pressure and temperature dependence hampers chemical modeling of flame systems. Recently developed simplified models to describe unimolecular processes include the calculation of rate constants for thermal unimolecular reactions and recombinations at the low pressure limit, at the high pressure limit and in the intermediate fall-off region. Comparison between two different applications of Troe's simplified model and a comparison between the simplified model and the classic RRKM theory are described.
Document ID
19810007776
Document Type
Conference Paper
Authors
Adams, G. F. (Ballistic Research Labs. Aberdeen Proving Ground, MD, United States)
Date Acquired
August 11, 2013
Publication Date
November 1, 1980
Publication Information
Publication: NASA. Langley Res. Center The 17th JANNAF Combust. Meeting, Vol. 2
Subject Category
PROPELLANTS AND FUELS
Distribution Limits
Public
Copyright
Other